Atmosphere and Pollution

Dual Award Higher tier shaded blue, separate science Chemistry shaded green

5.1 Formation and Composition of the Atmosphere

recall that originally the atmosphere of the Earth probably contained methane, ammonia, carbon dioxide and steam

Discuss the formation of the Earth, the loss of the first primitive atmosphere, and the formation of the atmosphere above solidified molten rocks.

explain the origin of the oceans by condensation of steam and their importance as gas reservoirs, particularly for carbon dioxide

Discuss what happened to the primitive atmosphere as the temperature cooled down: water vapour condensed to form oceans into which soluble gases dissolved (especially CO2).

explain that the first primitive plants released oxygen as a result of photosynthesis and that the amount of oxygen gradually increased

 

describe an experiment to determine the approximate percentage of oxygen in the atmosphere

Discuss possible substances which could remove oxygen from air.

recall how to test for carbon dioxide and water

Discuss tests for CO2 and H2O.

recall the composition of the atmosphere

Discuss gases which are present in the air in small amounts; emphasise that CO2 is present only at a concentration of 0.03%.

recall the composition of the atmosphere

 

explain how the carbon cycle helps to maintain atmospheric composition, i.e. carbon dioxide is added to the atmosphere by respiration and combustion and removed by photosynthesis and solution in water

Discuss the methods by which CO2 is added to and removed from the atmosphere.

explain how the carbon cycle helps to maintain atmospheric composition, i.e. carbon dioxide is added to the atmosphere by respiration and combustion and removed by photosynthesis and solution in water

 

5.2 The Nature, Properties and Uses of Noble Gases

recall the monatomic nature of noble gases

Consider the electronic configuration of the elements to elicit the fact that noble gases have eight electrons in their outer shells.

explain the monatomic nature of noble gases

A full outer shell provides the explanation for their monatomic and unreactive nature.

relate the uses of noble gases to their physical properties and lack of chemical reactivity

Obtain ‘Argon’ by breaking a lightbulb around a filemark under water and collecting the gas over an inverted funnel; this can be shown to be unreactive with e.g. burning Mg.

5.3 Atmospheric Pollution

recall that the combustion of fuels can produce the pollutants: carbon, carbon monoxide, sulphur dioxide and oxides of nitrogen

Test gas jars of SO2 and NO2 with Universal Indicator paper or solution.

recall the ways in which CO, SO2 and NOx are formed and how they are harmful

Explain the formation of CO, NOx and SO2 in car engines. Discuss how many people in the class are asthmatic and what they think are the reasons for their asthma - this leads to the effects of some of the pollutants. Consider briefly some of the sources other than combustion of fuels in car engines.

5.4 Fuels

understand that the vapours of volatile flammable materials are more dense than air and pose a fire hazard

Discuss why naked flames must be extinguished in petrol stations.

recall and explain the formation of the products of the complete and incomplete combustion (oxidation) of hydrocarbons

Recall that the products of complete combustion of hydrocarbon fuels are H2O and CO2. CO and/or C can be formed if insufficient O2 is present.

5.5 Energy Changes accompanying Physical and Chemical Changes

recall that changes of temperature often accompany reactions

Demonstrate reactions such as: concentrated H2SO4 added to water, burning Mg, Thermit reaction.

define an exothermic reaction as one in which heat energy is given out

 

define an endothermic reaction as one in which heat energy is taken in

 

give examples of exothermic and endothermic processes

 

explain the progress of a reaction, where relevant, in terms of first the breaking of covalent bonds and then the forming of other covalent bonds, (NB. Calculations involving average bond enthalpies (bond energies) are not required)

Discuss reaction of H2 with O2 to form H2O; for reaction to occur, H-H and O=O bonds have to be broken before O-H bonds formed.

recall that the breaking of bonds is endothermic and that the making of bonds is exothermic

Explain that energy is required to break existing bonds and energy is released when new bonds form. Explain that, in the reaction between H2 and O2, a lighted splint is required to provide energy for breaking existing bonds and energy is given out when new bonds form.

understand that most fuels contain carbon compounds and that combustion releases energy, carbon dioxide, and, often, water

 

recall that photosynthesis converts carbon dioxide and water into glucose and oxygen

 

understand that the overall process of photosynthesis is endothermic, that the source of energy is sunlight and that chlorophyll is essential to the process

 

understand that, as regards reactants and products, respiration is effectively the reverse of photosynthesis and is exothermic

 

write balanced equations for the overall processes of respiration and photosynthesis

 

understand the chemical reactions and energy changes involved in the carbon cycle

 

understand that CO2 may be involved in the warming of the Earth's atmosphere (the greenhouse effect)